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// Blog August 26, 2019

The Thermal Conductivity of Unfilled Plastics

The C-Therm Trident Thermal Conductivity Instrument provides a fast and easy way to measure thermal conductivity of plastics and polymers. 

FLEX Transient Plane Source Sensor testing thermal conductivity of polymer composite.
FLEX Transient Plane Source Sensor testing thermal conductivity of polymer composite.

Polymers are an important part of everyday life, and each day more research is being put in to develop new, more versatile, novel polymers. Testing the thermal conductivity of these polymers is paramount to determining their thermal performance under various conditions.

Both the Modified Transient Plane Source (MTPS) and Transient Plane Source (TPS) are both able to rapidly and accurately measure the thermal conductivity of polymers under a variety of environmental conditions. Meanwhile, the Transient Line Source (TLS) is able to measure the thermal conductivity of polymer melts. 

The thermal conductivities of common unfilled plastics such as teflon, PVC, and ABS can be found below. 

Thermal Conductivity of Unfilled Plastics (W/mK)1

Plastic Type
Commercial Name
Thermal Conductivity (W/mK
Acrylonitrile-butadiene-styrene
ABS
0.14 – 0.21
Acetal
Delrin
0.23 – 0.36
Cellulose acetate
CA
0.16 – 0.36
Diallyl phthalate
Dapon
0.31
Epoxy
 
0.19
Ethylcellulose
 
0.23
Ethylvinylacetate
 
0.08
Phenolic
 
0.17
Polyamide
Nylon 6-11-12-66
0.24 – 0.3
Polyaramide
Kevlar, Nomex fibers
0.04 – 0.13
Polycarbonate
PC
0.19 – 0.22
Polytetrafluorethylene
PTFE, Teflon
0.25
Polyethylene terephthalate
 
0.15 – 0.4
Polyethylene L
Low density
0.33
Polyethylene HD
High density
0.45 – 0.52
Polyimide
Kapton
0.10 – 0.35
Polymethylmethacrylate
PMMA, Acrylic, Perspex, Plexiglass
0.17 – 0.19
Polyphenylene oxide
PPO, Noryl
0.22
Polypropylene
PP
0.1 – 0.22
Polystyrene
PS
0.1 – 0.13
Polysulfone
 
0.26
Polyurethane
PUR
0.29
Polyvinylchloride
PVC
0.12 – 0.25
Polyvinylidene fluoride
Kynan
0.1 – 0.25
 
All values in the table are defined at room temperature. As a rule-of-thumb, the thermal conductivity increases with a few percent in the range 0-100°C. Only below very low temperatures (typically 40K), plastics show a clear decrease.  Fillers such as silver, copper, CNTs etc. typically cause a sharp increase in the thermal conductivity of a polymer composite. 
 
To find out more on what sensor is right for your polymer, or the services that C-Therm can provide, check out the resources below.
 
Method Selection Guide: Ideal for determining what sensor best fits your sample
Contract Testing Services: Thermal conductivity testing is available for those who only need a few samples tested
Trident Information: Helpful for anyone who needs to measure thermal conductivity often, or needs the flexibility for different materials. Talk to an expert today about what configuration will fit your technical needs.
This blog is a part of our Conductive Polymers application.
1Source: Electronics Cooling – Design, Materials, Compounds, Adhesives, Substrates, Number 2, Technial Data, Volume 7

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